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Merck
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重要文件

90660

Sigma-Aldrich

三苄胺

≥99.0% (NT)

同義詞:

TBA

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About This Item

線性公式:
(C6H5CH2)3N
CAS號碼:
分子量::
287.40
Beilstein:
2214682
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

≥99.0% (NT)

形狀

powder

mp

91-94 °C (lit.)

官能基

amine
phenyl

SMILES 字串

C(N(Cc1ccccc1)Cc2ccccc2)c3ccccc3

InChI

1S/C21H21N/c1-4-10-19(11-5-1)16-22(17-20-12-6-2-7-13-20)18-21-14-8-3-9-15-21/h1-15H,16-18H2

InChI 密鑰

MXHTZQSKTCCMFG-UHFFFAOYSA-N

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應用

三苄胺(TBA)是一种叔胺,可以用作:
  • 涉及 C−N 键形成反应的氮基源;
  • 用于通过有氧氧化缩合反应合成亚胺,即 N−亚苄基苄胺。
  • 作为萃取剂,用于分离和测定废水中的 Cr(VI)和Cr(III)。

TBA 还可以在硝酸铈铵(CAN)存在下进行脱苄基反应以形成二苄胺。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

399.2 °F - closed cup

閃點(°C)

204 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析證明 (COA)

Lot/Batch Number

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Copper-Catalyzed Oxidative Amination of Benzoxazoles via C- H and C- N Bond Activation: A New Strategy for Using Tertiary Amines as Nitrogen Group Sources.
Guo S, et al.
Organic Letters, 13(3), 522-525 (2010)
Chemoselective oxidative debenzylation of tertiary N-benzyl amines.
Bull SD, et al.
Chemical Communications (Cambridge, England), 165(5), 337-338 (2000)
Highly active and selective gold catalysts for the aerobic oxidative condensation of benzylamines to imines and one-pot, two-step synthesis of secondary benzylamines.
Grirrane A, et al.
J. Catal., 264(2), 138-144 (2009)
Céline Burnier et al.
Talanta, 192, 135-141 (2018-10-24)
Nowadays, Gas Chromatography Mass Spectrometry (GC-MS) is mainly used in forensic sciences but suffers from limitations when the analysed compounds are thermally instable as it is the case for THC-A (Tetrahydrocannabinolic Acid) which is converted into Δ9-THC (Δ9-Tetrahydrocannabinol) that subsequently
Yan Qu et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 58(9-10), 640-642 (2003-10-28)
Two compounds, (p-methoxyphenyl) diphenylmethanol (1) and tribenzylamine (2), were isolated from Humulus lupulus. Their structures were established on the basis of spectral evidence (MS, IR, NMR, HMBC, HMQC, 1H-1H COSY experiments). Compounds 1 and 2 were found as natural products

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