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Key Documents

903663

Sigma-Aldrich

t-BuDavePhos Pd G4

同義詞:

t-BuDavePhos G4 Palladacycle, t-BuDavePhos Palladacycle

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About This Item

經驗公式(希爾表示法):
C36H47N2O3PPdS
CAS號碼:
分子量::
725.23
分類程式碼代碼:
12161600
NACRES:
NA.22

形狀

powder or crystals

特點

generation 4

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

官能基

phosphine

相關類別

一般說明

tBuDavePhos Pd G4 is a fourth generation (G4) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. tBuDavePhos Pd G4 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

應用

tBuDavePhos Pd G4 will be used for a variety of C-C and C-N cross-coupling reactions.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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文章

G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.

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