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901368

Sigma-Aldrich

[Ir(dFppy)2(dtbbpy)]PF6

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About This Item

經驗公式（希爾表示法）:
C40H36F10IrN4P
CAS號碼:
1072067-44-7
分子量：:
985.92
分類程式碼代碼:
51171641
NACRES:
NA.23

形狀

powder or crystals

品質等級

100

反應適用性

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

活化光觸媒

465 nm

相關類別

應用

这种光催化剂很易于促进羧酸的烷化作用，以及通过金属光氧化还原催化的草酸脱羧交叉偶联。

产品可以和我们的光反应器一起使用：包括Penn PhD（Z744035）& SynLED 2.0 （Z744080）

其他說明

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[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析證明 (COA)

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Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S,et al.
European Journal of Inorganic Chemistry, 2013, 5329-5343 (2013)
Franck Le Vaillant et al.
Angewandte Chemie (International ed. in English), 54(38), 11200-11204 (2015-07-28)
Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes from readily available carboxylic
Timothy M Monos et al.
The Journal of organic chemistry, 81(16), 6988-6994 (2016-06-16)
We report a rapid, one-pot, operationally simple, and scalable preparation of valuable cationic heteroleptic iridium(III) polypyridyl photosensitizers. This method takes advantage of two consecutive microwave irradiation steps in the same reactor vial, avoiding the need for additional reaction purifications. A
Xiaheng Zhang et al.
Journal of the American Chemical Society (2016-10-11)
Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to

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