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Merck
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Key Documents

900855

Sigma-Aldrich

1,1,2,2-Tetrakis(4-bromophenyl)ethylene

同義詞:

1,1′,1′′,1′′′-(1,2-Ethenediylidene)tetrakis[4-bromobenzene]

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About This Item

經驗公式(希爾表示法):
C26H16Br4
CAS號碼:
分子量::
648.02
MDL號碼:
分類程式碼代碼:
12352103
NACRES:
NA.23

形狀

powder or crystals

品質等級

溶解度

DMF: soluble
DMSO: soluble
THF: soluble
dichloromethane: soluble

儲存溫度

2-8°C

一般說明

AIE (aggregation-induced emission)-active building block.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Natalia B Shustova et al.
Journal of the American Chemical Society, 133(50), 20126-20129 (2011-11-15)
Coordinative immobilization of functionalized tetraphenylethylene within rigid porous metal-organic frameworks (MOFs) turns on fluorescence in the typically non-emissive tetraphenylethylene core. The matrix coordination-induced emission effect (MCIE) is complementary to aggregation-induced emission. Despite the large interchromophore distances imposed by coordination to
Nathan D Rudd et al.
ACS applied materials & interfaces, 8(44), 30294-30303 (2016-10-14)
We have designed and synthesized an isoreticular series of luminescent metal-organic frameworks (LMOFs) by incorporating a strongly emissive molecular fluorophore and functionally diverse colinkers into Zn-based structures. The three-dimensional porous networks of LMOF-261, -262, and -263 represent a unique/new type
Sasanka Dalapati et al.
Journal of the American Chemical Society, 138(18), 5797-5800 (2016-04-26)
Highly luminescent covalent organic frameworks (COFs) are rarely achieved because of the aggregation-caused quenching (ACQ) of π-π stacked layers. Here, we report a general strategy to design highly emissive COFs by introducing an aggregation-induced emission (AIE) mechanism. The integration of

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