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重要文件

900472

Sigma-Aldrich

(R)-TolBINAP Pd G4

95%

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About This Item

經驗公式(希爾表示法):
C62H55NO3P2PdS
分子量::
1062.54
分類程式碼代碼:
12161600
NACRES:
NA.22

品質等級

化驗

95%

形狀

powder

特點

generation 4

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

官能基

phosphine

SMILES 字串

CC(C=C1)=CC=C1P(C2=CC=C(C)C=C2)C3=C(C4=C(P(C5=CC=C(C)C=C5)C6=CC=C(C)C=C6)C=CC7=C4C=CC=C7)C8=C(C=C3)C=CC=C8.C[NH+](C9=C(C=CC=C9)C%10=C%11C=CC=C%10)[Pd-]%11OS(C)(=O)=O

InChI 密鑰

WKGRPDDVBKRQJX-UHFFFAOYSA-M

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Nathaniel H Park et al.
Angewandte Chemie (International ed. in English), 54(28), 8259-8262 (2015-06-03)
In Pd-catalyzed C-N cross-coupling reactions, α-branched secondary amines are difficult coupling partners and the desired products are often produced in low yields. In order to provide a robust method for accessing N-aryl α-branched tertiary amines, new catalysts have been designed

文章

G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.

Global Trade Item Number

庫存單位GTIN
900472-1G4061826648100

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