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About This Item
經驗公式（希爾表示法）:
C6H2BBrF6KN
分子量：:
331.89
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
化驗
97%
形狀
solid
SMILES 字串
BrC1=C([B-](F)(F)F)C(C(F)(F)F)=CC=N1.[K+]
InChI
1S/C6H2BBrF6N.K/c8-5-4(7(12,13)14)3(1-2-15-5)6(9,10)11;/h1-2H;/q-1;+1
InChI 密鑰
WGDRKFJAJWNHQI-UHFFFAOYSA-N
應用
An organotrifluoroborate involved in:
Organotrifluoroborates as versatile and stable boronic acid surrogates.
- Nickel-catalyzed cross-coupling reactions and C-O activation
- Suzuki cross-coupling,
- Copper-catalyzed cross-coupling reactions
- Stereoselective Mukaiyama aldol reactions
Organotrifluoroborates as versatile and stable boronic acid surrogates.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Synthesis of 5-aryl- and 5-heteroaryl-7-carboxyl-8-hydroxyquinaldines through Suzuki cross-coupling reaction with potassium organotrifluoroborates
Synthesis, 4, 619-630 (2010)
Gary A Molander et al.
Organic letters, 12(18), 4022-4025 (2010-08-19)
A general method based on nickel-catalyzed C-O activation of various phenol derivatives with potassium (hetero)aryltrifluoroborates has been developed. A large number of heterobiaryls can be easily obtained with yields up to 99% using methanesulfonate cross-coupling partners.
J Michael Ellis et al.
The Journal of organic chemistry, 73(22), 9151-9154 (2008-10-16)
A new synthesis of 3,3'-bioxindoles is reported that is well suited for the preparation of unsymmetrical structures. In the key step, 3-hydroxy-3,3'-bioxindoles are constructed by Mukaiyama aldol reaction of 2-siloxyindoles with isatins. These tertiary carbinols are formed in high diastereoselectivities
Copper catalyzed cross-coupling reactions of diaryl ditellurides with potassium aryltrifluoroborate salts
Journal of the Brazilian Chemical Society, 20, 988-992 (2009)
Gary A Molander et al.
Organic letters, 12(24), 5783-5785 (2010-11-26)
A method for the cross-coupling of alkyl electrophiles with various potassium aryl- and heteroaryltrifluoroborates has been developed. Nearly stoichiometric amounts of organoboron species could be employed to cross-couple a large variety of challenging heteroaryl nucleophiles. Several functional groups were tolerated
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