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Key Documents

760714

Sigma-Aldrich

S-(4-Bromobutyl) thioacetate

96% (GC)

同義詞:

1-Butanethiol, 4-bromo-, acetate, Acetic acid, thio-,S-(4-bromobutyl) ester, Ethanethioic acid, S-(4-bromobutyl) ester

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About This Item

經驗公式(希爾表示法):
C6H11BrOS
CAS號碼:
分子量::
211.12
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

96% (GC)

形狀

liquid

包含

copper as stabilizer

成份

(copper wire added to bulk material for stabilization)

儲存條件

under inert gas

折射率

n20/D 1.518

密度

1.388 g/mL at 25 °C

儲存溫度

−20°C

SMILES 字串

CC(=O)SCCCCBr

InChI

1S/C6H11BrOS/c1-6(8)9-5-3-2-4-7/h2-5H2,1H3

InChI 密鑰

ABARMQVSPZAYRI-UHFFFAOYSA-N

一般說明

S-(4-Bromobutyl) thioacetate is used as a precursor in the formation of organic self-assembled monolayers (SAMs) on metals. Deprotection reactions can then converts the thioacetate group to thiol. These are chemisorbed onto metal surfaces to form self-assembled monolayers with a high degree of structural order. They are often used as a molecular template to form functional nanostructures.

應用

Used in the formation of Self-Assembled Monolayers on gold electrodes to modify its work function.

特點和優勢

High chemical stability in air or solution. Thioacetate prevents undesirable oxidation of thiol groups in oxygen containing atmosphere. Forms homogeneous interface structure in SAMs.

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Formation and Structure of Self-Assembled Monolayers of Octylthioacetates on Au (111) in Catalytic Tetrabutylammonium Cyanide Solution
Park, T., Kang, H., Choi, I., Chung, H., Ito, E., Hara, M., & Noh, J.
Bull. Korean Chem. Soc., 30(2), 441-441 (2009)
The Thioacetate-Functionalized Self-Assembled Monolayers on Au: Toward High-Performance Ion-Selective Electrode for Ag
Jin, J., Zhou, W. J., Chen, Y., Liu, Y. L., Sun, X. Q., & Xi, H. T.
Bull. Korean Chem. Soc., 35(2), 601-601 (2014)

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