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重要文件

750263

Sigma-Aldrich

Potassium 1-(phenylsulfonyl)-1H-indole-3-trifluoroborate

95%

同義詞:

Potassium 1-(phenylsulfonyl)-3-indoletrifluoroborate, Potassium 1-(phenylsulfonyl)-3-indolyltrifluoroborate

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About This Item

經驗公式(希爾表示法):
C14H10BF3KNO2S
分子量::
363.20
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

化驗

95%

形狀

solid

mp

283-290 °C

SMILES 字串

[K+].F[B-](F)(F)c1cn(c2ccccc12)S(=O)(=O)c3ccccc3

InChI

1S/C14H10BF3NO2S.K/c16-15(17,18)13-10-19(14-9-5-4-8-12(13)14)22(20,21)11-6-2-1-3-7-11;/h1-10H;/q-1;+1

InChI 密鑰

XLOGEONPZAROPE-UHFFFAOYSA-N

應用

Potassium 1-(phenylsulfonyl)-1H-indole-3-trifluoroborate can be used as a reactant in:
  • The palladium-catalyzed Suzuki-Miyaura α-arylation reaction.
  • The nucleophilic addition reactions.
  • The preparation of indole substituted borazaronaphthalene.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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存取文件庫

Method for Accessing Nitrogen-Containing, B-Heteroaryl-Substituted 2, 1-Borazaronaphthalenes
Davies GHM, et al.
The Journal of Organic Chemistry, 82(1), 549-555 (2017)
Oxyallyl Cation Capture via Electrophilic Deborylation of Organoboronates: Access to α , α `-Substituted Cyclic Ketones
Nguyen TN, et al.
Organic Letters, 21(19), 7837-7840 (2019)
Gary A Molander et al.
The Journal of organic chemistry, 78(8), 4123-4131 (2013-04-11)
A method has been developed for the Pd-catalyzed synthesis of α-(hetero)aryl esters and amides through a Suzuki-Miyaura cross-coupling reaction. This method avoids the use of strong base, does not necessitate inert or low temperature formation of reagents, and does not

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