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740810

Sigma-Aldrich

2-（十二烷基硫基硫代羰基硫基）-2-甲基丙酸五氟苯基酯

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About This Item

經驗公式（希爾表示法）:
C23H31F5O2S3
CAS號碼:
1174764-26-1
分子量：:
530.68
MDL號碼:
MFCD22417193
分類程式碼代碼:
12352100
PubChem物質ID:
329765442
NACRES:
NA.23

形狀

liquid

雜質

4-5% pentafluorophenol

折射率

n20/D 1.512

密度

1.203 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)Oc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C23H31F5O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-32-22(31)33-23(2,3)21(29)30-20-18(27)16(25)15(24)17(26)19(20)28/h4-14H2,1-3H3

InChI 密鑰

XBUCQRRMAZYXHN-UHFFFAOYSA-N

一般說明

需要帮助选择正确的RAFT试剂？请查阅RAFT试剂与单体的相容性表。

應用

用于受控自由基聚合的RAFT试剂，特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。链转移剂(CTA)

其他說明

该产品含有4-5%的五氟苯酚杂质。 该杂质通常不会干扰链转移剂

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

>230.0 °F

閃點（°C）

> 110 °C

分析證明 (COA)

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

文章

A Micro Review of Reversible Addition/Fragmentation Chain Transfer (RAFT) Polymerization

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Tools for Performing ATRP

Tools for Performing ATRP

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

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Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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