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重要文件

70863

Sigma-Aldrich

1-丁基-2,3-二甲基咪唑四氟硼酸盐

≥97.0%

同義詞:

[BDMIM][BF4]

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About This Item

經驗公式(希爾表示法):
C9H17BF4N2
CAS號碼:
分子量::
240.05
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥97.0%

形狀

liquid

雜質

≤1% water

mp

37 °C
37 °C

密度

1.198 g/mL at 20 °C (lit.)

SMILES 字串

F[B-](F)(F)F.CCCCn1cc[n+](C)c1C

InChI

1S/C9H17N2.BF4/c1-4-5-6-11-8-7-10(3)9(11)2;2-1(3,4)5/h7-8H,4-6H2,1-3H3;/q+1;-1

InChI 密鑰

VCAIYEJBOWHUGP-UHFFFAOYSA-N

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相關類別

一般說明

1-Butyl-2,3-dimethylimidazolium tetrafluoroborate is a task-specific ionic liquid.

應用

[bdmim]BF4 can be used as a solvent when lipase needs to be recycled during lipase-catalyzed transesterification with vinyl acetate as acyl donor. The [bdmim]BF4/toluene biphasic solvent forms an efficient system for the Negishi cross-coupling reaction between aryl zinc halides and aryl iodides.

其他說明

离子液体,适用于强碱性环境,如羟醛缩合反应

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves


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分析證明 (COA)

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Palladium catalyzed cross-couplings of organozincs in ionic liquids.
Sirieix J, et al.
Synlett, 2000(11), 1613-1615 (2000)
Chiral ionic phosphites and diamidophosphites: a novel group of efficient ligands for asymmetric catalysis
Gavrilov, Konstantin N., et al.
Advanced Synthesis & Catalysis, 349.4-5, 609-616 (2007)
Hydrolase-catalyzed Kinetic Resolution of 5-[4-(1-Hydroxyethyl) phenyl]-10, 15, 20-tris (pentafluorophenyl) porphyrin in Ionic Liquids
Ema, Tadashi, Tokuhiro Doi, and Takashi Sakai
Chemistry Letters (Jpn), 37.1, 90-91 (2007)
Enzyme-catalyzed reactions in ionic liquids
Moon, Yun Hee, et al.
Korean Journal of Chemical Engineering, 23.2, 247-263 (2006)
Self?Organization of Spherical, Core?Shell Palladium Aggregates by Laser?Induced and Thermal Decomposition of [Pd (PPh3) 4]
Ye, Enyi, et al.
Angewandte Chemie (International Edition in English), 118.7, 1138-1141 (2006)

文章

Task-Specific Ionic Liquids

Task-Specific Ionic Liquids (TSILs) for the selective liquid/liquid extraction of heavy metals from aqueous systems were first published by Robin D. Rogers et al. in the year 2001.

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