700665

(11bR)-2,6-二-9-菲基-4-羟基-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物

• 同義詞: (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
• 經驗公式（希爾表示法）: C₄₈H₂₉O₄P
• CAS號碼: 864943-22-6
• 分子量：: 700.72
• MDL號碼: MFCD12546016
• 分類程式碼代碼: 12352005
• PubChem物質ID: 329762222
• NACRES: NA.22

屬性

• 形狀: solid
• 品質等級: 100
• 光學活性: [α]22/D −44.0°, c = 1 in DMSO
• mp: 390-400 °C
• 官能基: phosphate
• 儲存溫度: −20°C
• SMILES 字串: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
• InChI: 1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
• InChI 密鑰: BVICVEIKBNVROI-UHFFFAOYSA-N

描述

應用

Catalyst for:

• Asymmetric hydrogenation cascade
• Enantioselective Friedel-Crafts reaction
• Asymmetric hydrogenation of 2-substituted quinolines
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
• Asymmetric transfer hydrogenation of substituted quinoxalines

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)