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Key Documents

686034

Sigma-Aldrich

氢化锂铝

greener alternative

hydrogen-storage grade

同義詞:

LAH, 丙氨酸锂, 四氢铝酸锂

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About This Item

線性公式:
LiAlH4
CAS號碼:
分子量::
37.95
EC號碼:
MDL號碼:
分類程式碼代碼:
26111700
PubChem物質ID:
NACRES:
NA.23

等級

hydrogen-storage grade

化驗

>99.95%

形狀

pellets

反應適用性

reagent type: reductant

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

125 °C (dec.) (lit.)

環保替代類別

SMILES 字串

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI 密鑰

OCZDCIYGECBNKL-UHFFFAOYSA-N

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一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

應用

Lithium aluminum hydride (LAH) is majorly used in hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).

分析報告

可按要求提供氢含量、XRD 谱图和金属纯度数据。

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1A - Water-react 1

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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A first-principles study of the electronic structure and stability of a lithium aluminum hydride for hydrogen storage
Song Y, et al.
The Journal of Physical Chemistry B, 110(13), 6906-6910 (2006)
Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6
Chen J, et al.
The Journal of Physical Chemistry B, 105(45), 11214-11220 (2001)
Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Damián E Bikiel et al.
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental

文章

Our research impacts on the hydrogen energy economy through the development of “smart” nanofilms for the protection of metal hydrides against air and moisture, while permitting release of hydrogen gas through these semi permeable nanofilms.

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