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Key Documents

615854

Sigma-Aldrich

N-甲基-d3-2-吡咯烷酮-d6

98 atom % D

同義詞:

1-甲基-d3-2-吡咯烷酮-d6

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About This Item

經驗公式(希爾表示法):
C5D9NO
CAS號碼:
分子量::
108.19
MDL號碼:
分類程式碼代碼:
12352200
PubChem物質ID:
NACRES:
NA.12

同位素純度

98 atom % D

品質等級

化驗

99% (CP)

bp

202 °C (lit.)

密度

1.125 g/mL at 25 °C

質量偏移

M+9

SMILES 字串

[2H]C([2H])([2H])N1C(=O)C([2H])([2H])C([2H])([2H])C1([2H])[2H]

InChI

1S/C5H9NO/c1-6-4-2-3-5(6)7/h2-4H2,1H3/i1D3,2D2,3D2,4D2

InChI 密鑰

SECXISVLQFMRJM-YNSOAAEFSA-N

一般說明

N-Methyl-d3-2-pyrrolidinone-d9 is isotopically labeled analogue of N-methyl-2-pyrrolidinone

應用

N-Methyl-d3-2-pyrrolidinone-d9 can be used to investigate the mechanistic study of base-catalyzed carbon-alkylation of potassium enolates with styrenes via a metal–ene reaction.

包裝

This product may be available from bulk stock and can be packaged on demand. For information on pricing, availability and packaging, please contact Stable Isotopes Customer Service.

象形圖

Exclamation markHealth hazard

訊號詞

Danger

危險分類

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

186.8 °F - closed cup

閃點(°C)

86 °C - closed cup


分析證明 (COA)

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Joshua P Barham et al.
Organic & biomolecular chemistry, 18(11), 2063-2075 (2020-02-27)
Base-catalyzed, C-alkylation of potassium (K) enolates with styrenes (CAKES) has recently emerged as a highly practical and convenient method for elaboration or synthesis of pharmaceutically-relevant cores. K enolate-type precursors such as alkyl-substituted heterocycles (pyridines, pyrazines and thiophenes), ketones, imines, nitriles

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