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569593

Sigma-Aldrich

4,4′-二甲基-2,2′-联吡啶

99.5%, purified by sublimation

同義詞:

2,2′-二(γ-甲基吡啶), 4,4′-二甲基-2,2′-二吡啶

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About This Item

經驗公式(希爾表示法):
C12H12N2
CAS號碼:
分子量::
184.24
Beilstein:
128995
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99.5%

形狀

solid

純化經由

sublimation

mp

169-174 °C (lit.)

SMILES 字串

Cc1ccnc(c1)-c2cc(C)ccn2

InChI

1S/C12H12N2/c1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12/h3-8H,1-2H3

InChI 密鑰

NBPGPQJFYXNFKN-UHFFFAOYSA-N

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應用

4,4′-Dimethyl-2,2′-dipyridyl (dmbipy) may be used as a ligand in the synthesis of :
  • carbonato-bridged triangular trinuclear compounds and tetranuclear hydroxo-bridged compounds
  • dmbipy-copper bridged complexes, which show variation in crystal geometries, thermal and magnetic properties

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訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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"Ferromagnetic trinuclear carbonato-bridged and tetranuclear hydroxo-bridged Cu (II) compounds with 4, 4'-dimethyl-2, 2'-bipyridine as ligand. X-ray structure, spectroscopy and magnetism"
Albada VAN, et al.
Inorgorganica Chimica Acta, 331(01), 208-215 (2002)
"Crystal Chemistry of the 4,4`-Dimethyl-2,2`bipyridine/Copper Bromide System"
Willett.DR, et al
Inorganic Chemistry, 40(17), 4342-4352 (2001)
Maxime Mourer et al.
Bioorganic & medicinal chemistry, 20(6), 2035-2041 (2012-03-01)
Various polycharged calix[4]arenes were assayed as anti-mycobacterial agents against Mycobacterium tuberculosis, H(37)Rv strain. The sulfonate, carboxylate and phosphonate anionic species displayed no activity. Cationic derivatives integrating four aminoethyl groups at the upper rim and two 6,6'-dimethyl-2,2'-bipyridyl- or 4,4'-dimethyl-2,2'-bithiazolyl subunits at
Yang-Hui Luo et al.
Dalton transactions (Cambridge, England : 2003), 43(44), 16937-16942 (2014-10-11)
A new iron(II) complex based on the 4,4'-dimethyl-2,2'-bipyridine ligand [Fe(4,4'-dmbpy)3(ClO4)(SCN)·3H2O (1·3H2O)] has been prepared and characterized. Structural studies and Hirshfeld surface analysis for complex 1·3H2O at three different temperatures (300, 240 and 130 K) are described. The UV-vis absorption spectrum
Tommy Siu-Ming Tang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(30), 10729-10740 (2015-06-23)
The synthesis, characterization, photophysics, lipophilicity, and cellular properties of new phosphorescent ruthenium(II) polypyridine complexes functionalized with a dibenzocyclooctyne (DIBO) or amine moiety [Ru(N^N)2 (L)](PF6 )2 are reported (L=4-(13-N-(3,4:7,8-dibenzocyclooctyne-5-oxycarbonyl) amino-4,7,10-trioxa-tridecanyl-aminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-DIBO, N^N=2,2'-bipyridine bpy (1 a), 1,10-phenanthroline phen (2 a); L=4-(13-amino-4,7,10-trioxa-tridecanylaminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-NH2 , N^N=bpy

文章

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Tools for Performing ATRP

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We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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