推薦產品
反應適用性
reaction type: Grignard Reaction
濃度
0.5 M in THF
bp
65 °C
密度
0.950 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
Cc1cc(C)cc([Mg]Br)c1
InChI
1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h4-6H,1-2H3;1H;/q;;+1/p-1
InChI 密鑰
XPXQQJMQESWIKM-UHFFFAOYSA-M
應用
3,5-Dimethylphenylmagnesium bromide solution can be used:
- As a starting material for the synthesis of diarylborinic acids, which on Suzuki coupling with vinyl triflate yield penultimate methyl ester.
- To prepare 3,5-dimethyl-p-terphenyl by reacting with biphenylsulfonate in the presence of dppfNiCl2 catalyst.
法律資訊
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訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
-0.0 °F - closed cup
閃點(°C)
-17.78 °C - closed cup
Preparation of unsymmetrical terphenyls via the nickel-catalyzed cross-coupling of alkyl biphenylsulfonates with aryl Grignard reagents
Tetrahedron, 60(21), 4589-4599 (2004)
Suzuki reaction of a diarylborinic acid: one-pot preparation and cross-coupling of bis (3, 5-dimethylphenyl) borinic acid
Organic Process Research & Development, 5(4), 450-451 (2001)
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