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一般說明
以 2-甲基喹啉-8-醇为原料,二氧化硒为氧化剂,经氧化制得 8-羟基-2-喹啉甲醛。
應用
8-羟基-2-喹啉甲醛(8-羟基喹啉-2-甲醛)可用于以下制备过程:
- 8-羟基-2-喹啉-1-氨基芘与 1-氨基芘的席夫碱反应
- ( E )-2-((2-(吡啶-2-基)肼基)甲基)喹啉-8-醇(与 2-肼基吡啶偶联)
- 8-羟基喹啉-2-甲醛肟
- 2-[(8-羟基喹啉)-2-甲基氨基乙基]-β- D -吡喃葡萄糖苷
其他說明
合成络合剂的结构单元
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
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Dalton transactions (Cambridge, England : 2003), 47(17), 6156-6165 (2018-04-19)
One-pot reaction between 8-hydroxyquinoline-2-carboxaldehyde (HQC) and tris(hydroxymethyl)aminomethane (TRIS) followed by in situ cyclization yielded an oxazolidine based ligand which produced four mononuclear complexes of MnII(1), CoII(2), NiII(3), ZnII(4), a tetranuclear iron (FeIII4) complex (5) and a trinuclear cobalt (CoIICoIII2) complex
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