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重要文件

498254

Sigma-Aldrich

硒氰酸苯酯

96%

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About This Item

線性公式:
C6H5SeCN
CAS號碼:
分子量::
182.08
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

96%

折射率

n20/D 1.603 (lit.)

bp

116-117 °C/12 mmHg (lit.)

密度

1.484 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

N#C[Se]c1ccccc1

InChI

1S/C7H5NSe/c8-6-9-7-4-2-1-3-5-7/h1-5H

InChI 密鑰

NODWRXQVQYOJGN-UHFFFAOYSA-N

一般說明

Phenyl selenocyanate is a selenenylation agent that can be prepared by reacting benzeneselenenyl chloride and trimethylsilyl cyanide.

應用

Phenyl selenocyanate may be used in the synthesis of:
  • benzeneselenol esters
  • 2-bromoethyl phenyl selenie dibromide
  • α,α-dioxy-β-phenylseleno carbonitriles
  • β-alkoxyalkyl phenyl selenide

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

228.2 °F - closed cup

閃點(°C)

109 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Cyanoselenenylation of ketene acetals. Synthesis of carbonyl-protected a-oxo carbonitriles.
Tomoda S, et al.
Chemistry Letters (Jpn), 11(11), 1733-1734 (1982)
A convenient synthesis of phenyl selenocyanate.
Tomoda S, et al.
Chemistry Letters (Jpn), 10(8), 1069-1070 (1981)
Aryl selenocyanates and aryl thiocyanates: reagents for the preparation of activated esters.
Grieco PA, et al.
The Journal of Organic Chemistry, 43(6), 1283-1285 (1978)
Synthesis of Aryl 2-Haloethyl Selenides and their Reactions with Potassium Selenocyanate.
Lindgren B.
Acta Chemica Scandinavica. Series B, 31(1), 1-6 (1977)
Facile oxyselenation of olefins in the presence of copper (II) or copper (I) chloride as catalyst.
Toshimitsu A, et al.
The Journal of Organic Chemistry, 45(10), 1953-1958 (1980)

文章

For microbiologists the most fundamental stain was developed in 1884 by the Danish bacteriologist Hans Christian Gram.

For microbiologists the most fundamental stain was developed in 1884 by the Danish bacteriologist Hans Christian Gram.

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