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Key Documents

481718

Sigma-Aldrich

五羰基铁

greener alternative

>99.99% trace metals basis

同義詞:

五羰基铁, 羰基铁

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About This Item

線性公式:
Fe(CO)5
CAS號碼:
分子量::
195.90
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

蒸汽密度

6.74 (vs air)

品質等級

蒸汽壓力

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

化驗

>99.99% trace metals basis

形狀

liquid

自燃溫度

122 °F

反應適用性

core: iron
reagent type: catalyst

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

折射率

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

密度

1.49 g/mL at 25 °C (lit.)

環保替代類別

儲存溫度

2-8°C

SMILES 字串

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI 密鑰

FYOFOKCECDGJBF-UHFFFAOYSA-N

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一般說明

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

用作以下过程的反应物:
  • 加成反应
  • 通过光解分解
  • 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
  • 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备

  • 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体
Iron(0) pentacarbonyl can be used:
  • To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
  • As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
  • To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

象形圖

FlameSkull and crossbones

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

5.0 °F - closed cup

閃點(°C)

-15 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Tetsu Mitsumata et al.
The journal of physical chemistry. B, 116(40), 12341-12348 (2012-09-15)
A new class of magnetoelastic gel that demonstrates drastic and reversible changes in storage modulus without using strong magnetic fields was obtained. The magnetic gel consists of carrageenan and carbonyl iron particles. The magnetic gel with a volume fraction of
Caixia Zhan et al.
Dalton transactions (Cambridge, England : 2003), 39(46), 11255-11262 (2010-10-23)
By using "click" chemistry between a diazide and a diiron model complex armed with two alkynyl groups, two polymeric diiron complexes (Poly-Py and Poly-Ph) were prepared. The two polymeric complexes were investigated using infrared spectroscopy, scanning electron microscopy (SEM), transmission
H Ohoyama et al.
The journal of physical chemistry. A, 115(40), 10888-10893 (2011-09-13)
The atomic alignment effect has been studied for the dissociative energy transfer reaction of metal carbonyls (Fe(CO)(5), Ni(CO)(4)) with the oriented Ar ((3)P(2), M(J) = 2). The emission intensity from the excited metal products (Fe*, Ni*) has been measured as
Ioan Silaghi-Dumitrescu et al.
Journal of the American Chemical Society, 130(3), 901-906 (2008-01-01)
Density functional theory studies on a series of Fe2(CO)6(PX)2 derivatives show the tetrahedrane to be the most stable for the alkyl (X = Me, tBu), P-H (X = H), and chloro (X = Cl) derivatives. However, butterfly diradical and planar
R A Toshkova et al.
Journal of ethnopharmacology, 109(3), 394-399 (2006-09-19)
A purified saponin mixture (PSM) from Astragalus corniculatus Bieb. protected significantly hamsters against the experimental Graffi myeloid tumor. The application of PSM increased the survival rates, prolonged mean survival time and the tumor growth was markedly reduced. A purified saponin

文章

Spin-based electronic (spintronic) devices offer significant improvement to the limits of conventional charge-based memory and logic devices which suffer from high power usage, leakage current, performance saturation, and device complexity.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

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