推薦產品
化驗
≥95.0%
mp
269-275 °C (lit.)
SMILES 字串
OB(O)c1ccc2ccccc2c1
InChI
1S/C10H9BO2/c12-11(13)10-6-5-8-3-1-2-4-9(8)7-10/h1-7,12-13H
InChI 密鑰
KPTRDYONBVUWPD-UHFFFAOYSA-N
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應用
用于研究芳基硼酸和2,2,2-三氟苯乙酮的对映选择性铑催化加成反应,生成手性叔三氟甲基醇类物质。也可用于研究芳基硼酸和腈的钯催化加成反应生成芳基酮,以及芳基硼酸和芳氧基腈的钯催化加成反应生成苯并呋喃。
其他說明
含有不定量的酸酐。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Chemical communications (Cambridge, England), (39), 4093-4095 (2006-10-07)
The catalytic asymmetric 1,2-addition of a series of arylboronic acids to 2,2,2-trifluoroacetophenones is described with high isolated yields (up to 96%) and good enantioselectivities (up to 83% ee) using a rhodium(I)/phosphoramidite catalyst.
Journal of fluorescence, 24(4), 1215-1224 (2014-05-27)
Blue light-emitting spiro[benzotetraphene-fluorene] (SBTF)-based host materials, 3-(1-naphthyl)-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] (1), 3-(2-naphthyl)-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] (2), and 3-[2-(6-phenyl)naphthyl]-10-naphthylspiro[benzo[ij]tetraphene-7,9'-fluorene] (3) were designed and prepared via multi-step Suzuki coupling reactions. Introducing various aromatic groups into SBTF core lead to a reduction in band gap and a determination of
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(1), 79-86 (2016-10-28)
Nuclear magnetic resonance is applied to investigate the relative positions and interactions between cationic and non-ionic carbohydrate-based surfactants in mixed micelles with D
Organic letters, 8(26), 5987-5990 (2006-12-15)
[Structure: see text] A cationic palladium complex catalyzed addition of arylboronic acids to nitriles to yield aryl ketones with moderate to good yields was developed. A one-step synthesis of benzofurans from phenoxyacetonitriles under the catalysis of [(bpy)Pd+(micro-OH)]2(-OTf)2 or [(bpy)Pd2+(H2O)2](-OTf)2 was
Bioorganic & medicinal chemistry letters, 19(10), 2642-2645 (2009-04-21)
Inhibition of the beta-carbonic anhydrases (CAs, EC 4.2.1.1) from the pathogenic fungi Cryptococcus neoformans (Can2) and Candida albicans (Nce103) with a series of aromatic, arylalkenyl- and arylalkylboronic acids was investigated. Aromatic, 4-phenylsubstituted- and 2-naphthylboronic acids were the best Can2 inhibitors
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