446955

烯丙基三甲氧基硅烷

95%

• 同義詞: Trimethoxy-2-propen-1-ylsilane, trimethoxy-2-propenylsilane
• 線性公式: H₂C=CHCH₂Si(OCH₃)₃
• CAS號碼: 2551-83-9
• 分子量：: 162.26
• Beilstein: 2350745
• EC號碼: 219-855-8
• MDL號碼: MFCD00053865
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24868309
• NACRES: NA.22

屬性

• 化驗: 95%
• 形狀: liquid
• 折射率: n20/D 1.405 (lit.)
• bp: 146-148 °C (lit.)
• 密度: 0.963 g/mL at 25 °C (lit.)
• SMILES 字串: CO[Si](CC=C)(OC)OC
• InChI: 1S/C6H14O3Si/c1-5-6-10(7-2,8-3)9-4/h5H,1,6H2,2-4H3
• InChI 密鑰: LFRDHGNFBLIJIY-UHFFFAOYSA-N

描述

應用

Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.

安全資訊

• 象形圖: GHS02,GHS07
• 訊號詞: Warning
• 危險聲明: H226,H315,H319,H335
• 防範說明: P210 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 114.8 °F - closed cup
• 閃點（°C）: 46 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter