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Merck
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重要文件

436860

Sigma-Aldrich

N,N-二异丙苯胺

97%

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About This Item

線性公式:
C6H5N[CH(CH3)2]2
CAS號碼:
分子量::
177.29
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.519 (lit.)

bp

95-96 °C/11 mmHg (lit.)

密度

0.91 g/mL at 25 °C (lit.)

官能基

amine

SMILES 字串

CC(C)N(C(C)C)c1ccccc1

InChI

1S/C12H19N/c1-10(2)13(11(3)4)12-8-6-5-7-9-12/h5-11H,1-4H3

InChI 密鑰

OVSARSKQWCLSJT-UHFFFAOYSA-N

一般說明

N,N-Diisopropylaniline is an N,N-dialkylaniline. Its borane adducts have been prepared and reported as hydroborating agents. Thermal dissociation of the borane-N,N-diisopropylaniline adduct has been reported to afford gaseous diborane. N,N-Diisopropylaniline is a diisoproplyamino derivative that can be prepared by reacting bromobenzene with diisopropylamine.

應用

N,N-Diisopropylaniline was used for the synthesis of 4-diisopropylamino benzonitrile. It may be used for the synthesis of 6-(4-bromophenyl)-3-methoxy-5-methyl-8-oxabicyclo[3.2.1]octa-3,6-dien-2-one and N,N,N′,N′-tetraisopropylbenzidine.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

183.2 °F - closed cup

閃點(°C)

84 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Synthesis of N,N,N',N'-tetraalkylbenzidines through oxidative coupling of N,N-dialkylarylamines induced by SbCl5.
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Dual fluorescence and fast intramolecular charge transfer with 4-(diisopropylamino) benzonitrile in alkane solvents.
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Brown et al.
The Journal of organic chemistry, 65(15), 4655-4661 (2000-08-26)
Several N,N-diethyl-tert-alkylamines, such as N,N-diethyl-2-methyl-2-butylamine (1, t-PentNEt2), N,N-diethyl-2,3-dimethyl-2-butylamine (2, t-HexNEt2), N,N-diethyl-2,3,3-trimethyl-2-butylamine (3, t-HeptNEt2), and N,N-diethyl-1,1,3,3-tetramethylbutylamine (4, t-OctNEt2) with varying steric bulk around nitrogen (by changing the tert-alkyl group) have been prepared and examined as borane carriers. The complexing ability of

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