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Merck
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文件

417599

Sigma-Aldrich

4-甲氧基苯硼酸

≥95.0%

同義詞:

对甲氧基苯硼酸

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About This Item

線性公式:
CH3OC6H4B(OH)2
CAS號碼:
分子量::
151.96
Beilstein:
2936912
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

化驗

≥95.0%

形狀

powder

mp

204-206 °C (lit.)

SMILES 字串

COc1ccc(cc1)B(O)O

InChI

1S/C7H9BO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3

InChI 密鑰

VOAAEKKFGLPLLU-UHFFFAOYSA-N

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應用

试剂用于
  • Suzuki-Miyaura 交叉偶联反应
  • 钯催化的直接芳基化
  • 水相钯催化芳基化 Suzuki-Miyaura 法高效合成
  • 钯催化的立体选择性 Heck 型反应
  • 串联型钯 (II) 催化的氧化 Heck 反应和分子内 C-H 酰胺化反应
  • 铜介导芳基硼酸与氟烷基碘的无连接有氧氟烷基化反应
  • 钌催化直接芳基化
  • Rh 催化的不对称共轭加成
  • 无配体铜催化偶联

制备过程中使用的试剂
  • 硫代甲酰胺钯配合物作为 Suzuki 偶联催化剂的研究
  • 具有光物理属性的推拉型芳基乙烯基二嗪发色团

其他說明

含不定量的酸酐

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


分析證明 (COA)

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Maria Makrinich et al.
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Materials (Basel, Switzerland), 12(17) (2019-08-29)
Anthracene-based semiconductors are a class of molecules that have attracted interest due to their air stability, planarity, potential for strong intermolecular interactions, and favorable frontier molecular orbital energy levels. In this study seven novel 9,10-anthracene-based molecules were synthesized and their
Kosuke Ishijima et al.
Dalton transactions (Cambridge, England : 2003), 49(44), 15612-15621 (2020-09-24)
Benzo[b]arsole derivatives, being arsenic analogues of indole, were synthesized by utilizing a safely prepared arsenic precursor. The structural and photophysical properties of the obtained 2-arylbenzo[b]arsoles were experimentally and computationally studied in comparison with those of 1,2,5-triarylarsoles and 9-phenylarsafluorene. It was
M Lakshmi Kantam et al.
The Journal of organic chemistry, 71(25), 9522-9524 (2006-12-02)
N-Arylation of imidazoles and amines with arylboronic acids was accomplished with copper-exchanged fluorapatite (CuFAP) in methanol at room temperature. The products N-arylimidazoles and N-arylamines were isolated in good to excellent yields. A variety of arylboronic acids were converted to the
Elangovan Sindhuja et al.
Dalton transactions (Cambridge, England : 2003), 41(17), 5351-5361 (2012-03-09)
A simple route to synthesise palladium(II) complexes from the reaction of N-substituted pyridine-2-thiocarboxamide ligands and PdCl(2)(PPh(3))(2) has been developed. The new complexes are very soluble in common solvents and have been fully characterised (elemental analysis, FT-IR, (1)H, (31)P, (13)C-NMR), including

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