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380210

Sigma-Aldrich

1,1′-偶氮双(环己烷甲腈)

98%

同義詞:

1,1'-偶氮(氰基环己烷), ACHN, VAZO 催化剂 88 自由基源

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About This Item

線性公式:
NCC6H10N=NC6H10CN
CAS號碼:
分子量::
244.34
Beilstein:
960744
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

98%

形狀

solid

mp

114-118 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

N#CC1(CCCCC1)\N=N\C2(CCCCC2)C#N

InChI

1S/C14H20N4/c15-11-13(7-3-1-4-8-13)17-18-14(12-16)9-5-2-6-10-14/h1-10H2/b18-17+

InChI 密鑰

KYIKRXIYLAGAKQ-ISLYRVAYSA-N

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一般說明

1,1′-偶氮双(环己烷甲腈)(AHCN)是对热稳定的引发剂,可用于自由基聚合。 可溶于甲醇、二甲基甲酰胺(DMF)等多种溶剂。

應用

作为比 AIBN 更加有效的自由基引发剂,已被用于引发主要的自由基反应。

象形圖

FlameExclamation mark

訊號詞

Danger

危險分類

Eye Irrit. 2 - Self-react. D - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

5.2 - Organic peroxides and self-reacting hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


分析證明 (COA)

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文章

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We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Tools for Performing ATRP

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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