推薦產品
化驗
98%
形狀
liquid
折射率
n20/D 1.409 (lit.)
bp
140-142 °C (lit.)
密度
0.798 g/mL at 25 °C (lit.)
SMILES 字串
CC(C)(C)C(=C)O[Si](C)(C)C
InChI
1S/C9H20OSi/c1-8(9(2,3)4)10-11(5,6)7/h1H2,2-7H3
InChI 密鑰
PEHJULPJEVIIFJ-UHFFFAOYSA-N
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一般說明
(1-tert-Butylvinyloxy)trimethylsilane is a silyl enol. It belongs to organosilicone class of compounds. Enthalpy of vaporization of (1-tert-Butylvinyloxy)trimethylsilane at boiling point has been reported.
應用
(1-tert-Butylvinyloxy)trimethylsilane ((2,2-Dimethyl-1-methylenepropoxy)trimethylsilane) may be used in the synthesis of cis-3,3-dimethyl-1-(6-phenethyl-3,6-dihydro-2H-pyran-2-yl)butan-2-one.
(1-tert-Butylvinyloxy)trimethylsilane may be used in the preparation of 1-(4-bromophenyl)-4,4-dimethylpentan-3-one.
訊號詞
Warning
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
75.2 °F - closed cup
閃點(°C)
24 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Yaws CL.
Thermophysical Properties of Chemicals and Hydrocarbons, 574-574 (2014)
Salvatore Ferla et al.
Journal of medicinal chemistry, 57(18), 7702-7715 (2014-08-26)
The synthesis of imidazole styrylbenzamide, tert-butyl styrylimidazole, and tert-butyl styrylsulfonate derivatives is described. Evaluation of binding affinity and inhibitory activity against CYP24A1 identified the imidazole styrylbenzamides as potent inhibitors of CYP24A1, having selectivity with respect to CYP27B1 comparable with or
Robert J Hinkle et al.
Tetrahedron, 65(34), 6834-6839 (2010-02-18)
The rapid synthesis of cis-2,6-disubstituted dihydropyrans is achieved in a three-component, one-pot cascade reaction. BiBr(3)-ediated addition of ketene silyl acetals or silyl enol ethers to beta,gamma-unsaturated cis-4-trimethylsilyl-3-butenal provides a Mukaiyama aldol adduct containing a vinylsilane moiety tethered to a silyl
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