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Key Documents

370207

Sigma-Aldrich

4,6-二甲基-2-吡喃酮

98%

同義詞:

4,6-二甲基-2H-吡喃-2-酮

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About This Item

經驗公式(希爾表示法):
C7H8O2
CAS號碼:
分子量::
124.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

solid

mp

48-50 °C (lit.)

SMILES 字串

CC1=CC(C)=CC(=O)O1

InChI

1S/C7H8O2/c1-5-3-6(2)9-7(8)4-5/h3-4H,1-2H3

InChI 密鑰

IXYLIUKQQQXXON-UHFFFAOYSA-N

基因資訊

human ... CYP1A2(1544)

一般說明

4,6-Dimethyl-α-pyrone was immobilized in a guanidinium-sulfonate-calixarene (G4C) crystalline network, which upon exposure to ultraviolet irradiation, transforms the entrapped 4,6-dimethyl-α-pyrone into a 4,6-dimethyl-β-lactone. Thin solid films layers of 4,6-dimethyl-α-pyrone on UV irradiation at -190°C were investigated.

應用

4,6-Dimethyl-α-pyrone (Me21) has been used in the preparation of G4C{Me21} via reacting with tetra-p-sulfocalix[4]arene (C) and guanidine hydrochloride (GCl). It may be used in the preparation of host-guest complex G4C{Me21} by reacting with crystalline guanidinium-sulfonate-calixarene (G4C). This complex on UV irradiation afforded 1,3-dimethylcyclobutadiene (Me2CBD).

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


分析證明 (COA)

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Yves-Marie Legrand et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(36), 10021-10028 (2011-09-08)
Cyclobutadiene (CBD), the smallest cyclic hydrocarbon bearing conjugated double bonds, has long intrigued chemists because of its chemical characteristics. The question of whether the molecule could be prepared at all has been answered, but the parent compound and its unperturbed
Yves-Marie Legrand et al.
Science (New York, N.Y.), 329(5989), 299-302 (2010-07-22)
Cyclobutadiene (CBD), the smallest cyclic hydrocarbon bearing conjugated double bonds, has long intrigued chemists on account of its strained geometry and electronic instability, but the parent compound and its unperturbed derivatives have thus far eluded crystallographic characterization. In this work

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