365270

α-溴苯乙酸甲酯

97%

• 線性公式: C₆H₅CH(Br)CO₂CH₃
• CAS號碼: 3042-81-7
• 分子量：: 229.07
• MDL號碼: MFCD00013535
• 分類程式碼代碼: 12352100
• PubChem物質ID: 24862500
• NACRES: NA.22

屬性

• 化驗: 97%
• 形狀: liquid
• 折射率: n20/D 1.553 (lit.)
• bp: 113 °C/3 mmHg (lit.)
• 密度: 1.455 g/mL at 25 °C (lit.)
• 官能基: bromo; ester; phenyl
• 儲存溫度: 2-8°C
• SMILES 字串: COC(=O)C(Br)c1ccccc1
• InChI: 1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
• InChI 密鑰: NHFBYYMNJUMVOT-UHFFFAOYSA-N

描述

一般說明

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

應用

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.

安全資訊

• 象形圖: GHS05
• 訊號詞: Danger
• 危險聲明: H314
• 防範說明: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• 危險分類: Skin Corr. 1B
• 儲存類別代碼: 8A - Combustible corrosive hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 235.4 °F - closed cup
• 閃點（°C）: 113 °C - closed cup
• 個人防護裝備: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter