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Key Documents

359327

Sigma-Aldrich

N-己基甲胺

96%

同義詞:

N-甲基己胺

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About This Item

線性公式:
CH3NH(CH2)5CH3
CAS號碼:
分子量::
115.22
Beilstein:
1731685
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

96%

形狀

liquid

折射率

n20/D 1.416 (lit.)

bp

140-142 °C (lit.)

密度

0.76 g/mL at 25 °C (lit.)

官能基

amine

SMILES 字串

CCCCCCNC

InChI

1S/C7H17N/c1-3-4-5-6-7-8-2/h8H,3-7H2,1-2H3

InChI 密鑰

XJINZNWPEQMMBV-UHFFFAOYSA-N

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一般說明

N-Hexylmethylamine is an acyclic secondary amine. Ruthenium-catalyzed reaction of N-hexylmethylamine with styrene has been reported. Transition metal-catalyzed intermolecular hydroamination of N-hexylmethylamine with 2-vinylnaphthalene has been reported.

應用

N-Hexylmethylamine may be used in the synthesis of dialkyldithiocarbamato cadmium complexes Cd[S2CNRR′]2.

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Flam. Liq. 3 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

87.8 °F - closed cup

閃點(°C)

31 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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A transition metal-catalyzed intermolecular hydroamination of vinylarenes with alkylamines is reported. The combination of Pd(O2CCF3)4, DPPF, and TfOH was the most effective catalyst of those tested. Control experiments without palladium, acid, or ligand all occurred in low yield. The reaction

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