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About This Item
線性公式:
C2H5CH(C6H5)COCl
CAS號碼:
分子量：:
182.65
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
品質等級
化驗
98%
形狀
liquid
折射率
n20/D 1.516 (lit.)
bp
122-125 °C/20 mmHg (lit.)
密度
1.093 g/mL at 25 °C (lit.)
SMILES 字串
CCC(C(Cl)=O)c1ccccc1
InChI
1S/C10H11ClO/c1-2-9(10(11)12)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3
InChI 密鑰
QGXMHCMPIAYMGT-UHFFFAOYSA-N
一般說明
The kinetic resolution of racemic 2-phenylbutyryl chloride by sterically hindered chiral secondary alcohols has been evaluated. 2-Phenylbutyryl chloride reacts with 4-methoxybenzoyl chloride catalyzed by PdBr(Ph)(PPh3)2 to yield 1-(4-methoxyphenyl)-2-phenyl-2-buten-1-one.
應用
(R)-(-)-2-phenylbutyryl chloride may be employed as chiral reagent for the determination of dopamine and dopamine-derived salsolinol and norsalsolinol in human brain by GC-MS method. Chiral (S)-(+)-2-phenylbutyryl chloride may be used as derivatization reagent for the hydroxyl groups during the GC-MS assay for the enantiomers of 1,2-propanediol, 1,3-butanediol, 1,3-pentanediol and their corresponding hydroxyacids in biological fluids.
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
儲存類別代碼
8A - Combustible, corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
208.4 °F - closed cup
閃點（°C）
98 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
Determining the absolute configuration of hindered secondary alcohols-a modified
Barnekow DE and Cardellina II JH.
Tetrahedron Letters, 30(28), 3629-3632 (1989)
F Musshoff et al.
Forensic science international, 113(1-3), 359-366 (2000-09-09)
Using a solid-phase extraction procedure and a gas chromatographic-mass spectrometric (GC/MS) method the levels of dopamine and the levels of dopamine-derived salsolinol (SAL) and norsalsolinol (NorSAL) were determined in human brain areas involved in the etiology of alcoholism, parkinsonism and
L Powers et al.
Analytical biochemistry, 221(2), 323-328 (1994-09-01)
We developed gas chromatographic-mass spectrometric assays for the enantiomers of 1,2-propanediol, 1,3-butanediol, 1,3-pentanediol, and their corresponding hydroxyacids, lactate, beta-hydroxybutyrate, and beta-hydroxypentanoate (3-hydroxyvalerate) in biological fluids. The corresponding ketoacids, acetoacetate and beta-ketopentanoate, can be assayed simultaneously by pretreating the samples with
Novel synthesis of. alpha.,. beta.-unsaturated ketones by the palladium-catalyzed arylation of ketenes with aroyl chlorides or the decarbonylative cross-condensation of acyl halides.
Mitsudo T, et al.
The Journal of Organic Chemistry, 52(15), 3186-3192 (1987)
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