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Merck
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Key Documents

335789

Sigma-Aldrich

2,4-二氟氯苯

98%

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About This Item

線性公式:
ClC6H3F2
CAS號碼:
分子量::
148.54
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.475 (lit.)

bp

127 °C (lit.)

密度

1.353 g/mL at 25 °C (lit.)

官能基

chloro
fluoro

SMILES 字串

Fc1ccc(Cl)c(F)c1

InChI

1S/C6H3ClF2/c7-5-2-1-4(8)3-6(5)9/h1-3H

InChI 密鑰

AJCSNHQKXUSMMY-UHFFFAOYSA-N

應用

1-Chloro-2,4-difluorobenzene was used in the preparation of series of benzonorbornadienes. It was also used in the preparation of difluoroarenes.

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

91.4 °F - closed cup

閃點(°C)

33 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Jason T Manka et al.
The Journal of organic chemistry, 69(6), 1967-1971 (2004-04-03)
Aryldiazo substituents were used in nucleophilic aromatic substitution reactions of halogens. The Ph-N=N- group activates ortho fluorine atoms toward alkylthiolation under mild conditions. In contrast, the Me(2)N-C(6)H(4)-N=N- group has virtually no activation effect in nucleophilic aromatic substitution, and serves as
K C Caster et al.
The Journal of organic chemistry, 66(9), 2932-2936 (2001-04-28)
This report details the synthesis of several benzonorbornadienes by Diels--Alder cycloaddition of cyclopentadiene derivatives with substituted benzyne intermediates, which were generated by low-temperature metal--halogen exchange of halobenzenes. General conditions were developed, allowing synthesis of most benzonorbornadienes described herein at the

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