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Merck
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重要文件

316385

Sigma-Aldrich

氧化铝负载氟化钾

greener alternative

extent of labeling: 40 wt. % loading

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About This Item

線性公式:
KF
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.23
形狀:
solid

形狀

solid

品質等級

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

標籤範圍

40 wt. % loading

環保替代類別

SMILES 字串

[F-].[K+]

InChI

1S/FH.K/h1H;/q;+1/p-1

InChI 密鑰

NROKBHXJSPEDAR-UHFFFAOYSA-M

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

Green etherification reagent of choice according to Glaxo-Smith-Kline's reagent guide.

Synthesis of diaryl ethers, diaryl thioethers, and diarylamines mediated by potassium fluoride-alumina and 18-crown-6
Potassium fluoride loaded alumina can be used to catalyze:
  • Dehydration of alkyl and aryl aldoximes into nitriles may be catalyze by potassium fluoride loaded on alumina.
  • Palladium-catalysed reactions to prepare allylic thiol derivatives.
  • N-Alkylation of carboxamides.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

防範說明

危險分類

Acute Tox. 4 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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分析證明 (COA)

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Potassium fluoride doped on alumina: An efficient catalyst for conversion of aldoximes into nitriles.
Movassagh B and Shokri S
Synthetic Communications, 35(6), 887-890 (2005)
N-Alkylation of amides and N-heterocycles with potassium fluoride on alumina.
Yamawaki J, et al.
Chemistry Letters (Jpn), 10(8), 1143-1146 (1981)
Microwave mediated palladium-catalysed reactions on potassium fluoride/alumina without use of solvent.
Villemin D and Caillot F
Tetrahedron Letters, 42(4), 639-642 (2001)
Deniz Ekinci et al.
Bioorganic & medicinal chemistry, 19(2), 744-748 (2011-01-08)
Carbonic anhydrase (CA; EC 4.2.1.1) was purified from the gill of the teleost fish Dicentrarchus labrax (European seabass). The purification procedure consisted of a single step affinity chromatography on Sepharose 4B-tyrosine-sulfanilamide. The enzyme was purified 84.9-fold with a yield of

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