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Merck
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文件

301868

Sigma-Aldrich

4,7-菲咯啉

98%

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About This Item

經驗公式(希爾表示法):
C12H8N2
CAS號碼:
分子量::
180.21
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

mp

172-174 °C (lit.)

SMILES 字串

c1cnc2ccc3ncccc3c2c1

InChI

1S/C12H8N2/c1-3-9-10-4-2-8-14-12(10)6-5-11(9)13-7-1/h1-8H

InChI 密鑰

DATYUTWESAKQQM-UHFFFAOYSA-N

一般說明

4,7-Phenanthroline reacts with ruthenium carbonyl to yield cyclometalated derivatives.

應用

4,7-Phenanthroline was used in preparation of:
  • cyclic tetranuclear half-sandwich ruthenium(II) complexes
  • positively charged homochiral cyclic trinuclear metallacalix[3]arene species

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Dam. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


分析證明 (COA)

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Julien Frey et al.
Journal of the American Chemical Society, 130(33), 11013-11022 (2008-07-26)
Variously substituted coordinating rigid rods have been synthesized which incorporate a central 4,7-phenanthroline nucleus attached to two 2-pyridyl groups via its 3 and 8 positions, so as to yield bis-bidentate chelates, the two-coordinating axes of the chelates being parallel to
Miguel A Galindo et al.
Journal of inorganic biochemistry, 102(5-6), 1025-1032 (2008-01-12)
The reaction between [(eta(6)-p-cymene)Ru(H2O)3]X2 and 4,7-phenanthroline (phen) leads to the formation of the rectangular tetranuclear complexes [(eta(6)-p-cymene)4Ru4(mu-4,7-phen-N4,N7)(2)(mu-OH)4]X4 (X=NO3, 1a; SO3CF3, 1b) which have been structurally characterised by X-ray crystallography. 1H NMR spectroscopic studies suggest the presence of a partially dissociated
Miguel A Galindo et al.
Dalton transactions (Cambridge, England : 2003), (10)(10), 1563-1566 (2004-07-15)
Reaction of [(dach)Pd(NO3)2] entities (dach = (R,R)-1,2-diaminocyclohexane, (S,S)-1,2-diaminocyclohexane) and 4,7-phenanthroline (phen) providing, respectively, 90 and 120 degrees bond angles, leads to the formation of two novel positively charged homochiral cyclic trinuclear metallacalix[3]arene species [((R,R)-1,2-diaminocyclohexane)Pd(phen)]3(NO3)6 (2a) and [((S,S)-1,2-diaminocyclohexane)Pd(phen)]3(NO3)6 (2b). These species
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Archives of biochemistry and biophysics, 300(1), 169-177 (1993-01-01)
Porphobilinogen synthase (PBGS) is essential to all life forms; in mammals it is definitively established that Zn(II) is required for activity. The literature regarding the metal requirement for PBGS in other animals, plants, and bacteria neither establishes nor disproves a
V Arluison et al.
Biochemistry, 37(20), 7268-7276 (1998-06-04)
RNA:pseudouridine synthetase (Pus1) from Saccharomyces cerevisiae is a multisite specific enzyme that catalyzes the formation of pseudouridine at positions 34 and 36 of intron-containing precursor tRNAIle and at positions 27 and/or 28 of several yeast tRNAs. In this paper we

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