298352

(1S)-(-)-2,10-樟脑磺内酰胺

98%

• 同義詞: (-)-10,2-樟脑磺内酰胺, (-)-exo-10,2-莰烷磺内酰胺, (1S,5R)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.0^1,5]癸烷-3,3-二氧化物, [3aS-(3aα,6α,7aβ)]-六氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物
• 經驗公式（希爾表示法）: C₁₀H₁₇NO₂S
• CAS號碼: 94594-90-8
• 分子量：: 215.31
• Beilstein: 83811
• MDL號碼: MFCD00066271
• 分類程式碼代碼: 12352005
• PubChem物質ID: 24857980
• NACRES: NA.22

屬性

• 品質等級: 200
• 化驗: 98%
• 形狀: solid
• 光學活性: [α]19/D −32°, c = 5 in chloroform
• mp: 181-183 °C (lit.)
• SMILES 字串: [H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C
• InChI: 1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1
• InChI 密鑰: DPJYJNYYDJOJNO-NQMVMOMDSA-N

描述

一般說明

(1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.

應用

(1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.

安全資訊

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves