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一般說明
已经研究了氯甲烷在金属交换的沸石ZSM-5催化剂上与碱土金属和一些过渡金属的转化反应 。据报道,在用甲烷生产汽油的过程中,氯甲烷是一种化学中间体。已通过 原位 FTIR 光谱和催化试验 研究了 HSAPO-34 上氯甲烷向轻烯烃的催化转化。氯甲烷是一种气态的天然产物,参与了 PheUinus pomaceus 的甲基化过程 。氯甲烷在木质素降解真菌藜芦醇生物合成中作为甲基供体 。
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法律資訊
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
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軟管倒鉤
產品號碼
描述
訂價
訊號詞
Danger
危險分類
Carc. 2 - Flam. Gas 1B - Ozone 1 - Press. Gas Liquefied gas - Repr. 2 - STOT RE 2 Inhalation
儲存類別代碼
2A - Gases
水污染物質分類(WGK)
WGK 2
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。
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Highly efficient catalytic conversion of chloromethane to light olefins over HSAPO-34 as studied by catalytic testing and in situ FTIR.
J. Catal., 238(1), 46-57 (2006)
Conversion of chloromethane over metal-exchanged ZSM-5 to higher hydrocarbons.
Applied Catalysis, 75(1), 133-152 (1991)
Applied and environmental microbiology, 56(11), 3450-3457 (1990-11-01)
Chloromethane, a gaseous natural product implicated in methylation processes in Phellinus pomaceus, has been shown to act as methyl donor in veratryl alcohol biosynthesis in the lignin-degrading fungi Phanerochaete chrysosporium, Phlebia radiata, and Coriolus versicolor, none of which released detectable
The global chloromethane cycle: biosynthesis, biodegradation and metabolic role.
Natural product reports, 17(4), 337-348 (2000-10-03)
FEMS microbiology ecology, 77(2), 438-448 (2011-05-07)
Chloromethane gas is produced naturally in the phyllosphere, the compartment defined as the aboveground parts of vegetation, which hosts a rich bacterial flora. Chloromethane may serve as a growth substrate for specialized aerobic methylotrophic bacteria, which have been isolated from
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US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube
US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
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