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重要文件

288462

Sigma-Aldrich

三溴化磷

≥99.99% trace metals basis

同義詞:

溴化磷(III)

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About This Item

線性公式:
PBr3
CAS號碼:
分子量::
270.69
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.23
形狀:
liquid
化驗:
≥99.99% trace metals basis

蒸汽壓力

0.27 psi ( 54 °C)

品質等級

化驗

≥99.99% trace metals basis

形狀

liquid

折射率

n20/D 1.697 (lit.)

bp

175 °C (lit.)

mp

−41.5 °C (lit.)

密度

2.88 g/mL at 20 °C (lit.)

SMILES 字串

BrP(Br)Br

InChI

1S/Br3P/c1-4(2)3

InChI 密鑰

IPNPIHIZVLFAFP-UHFFFAOYSA-N

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一般說明

Phosphorus tribromide (PBr3) is a phosphorus halide that can be used as a reactive phosphorylating agent for the formation of multifunctional thiophenes.

應用

PBr3 can be used as an acceptor molecule in the formation of donor-acceptor complexes. It can also be used in the phosphorylation of arylphospholes which can further be utilized in the synthesis of phosphonic amides.

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Phosphorylation of 2-(3-methyl-1, 3-diazabuten-1-yl)-3-ethoxycarbonylthiophenes with phosphorus (III) halides
Pinchuk AM, et al.
Heteroatom Chem., 12(7), 641-651 (2001)
Site-selective phosphorylation of arylphospholes through reaction with phosphorus tribromide
Keglevich G, et al.
Journal of Organometallic Chemistry, 643(11), 32-38 (2002)
Donor-acceptor complexes between organoamines and phosphorus tribromide
Muller G, et al.
Zeitschrift fur Naturforschung B, 56(11), 1163-1171 (2001)
Andrey S Mereshchenko et al.
Nature chemistry, 7(7), 562-568 (2015-06-24)
'Roaming' is a new and unusual class of reaction mechanism that has recently been discovered in unimolecular dissociation reactions of isolated molecules in the gas phase. It is characterized by frustrated bond cleavage, after which the two incipient fragments 'roam'

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