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About This Item
經驗公式(希爾表示法):
C5H11NO2
CAS號碼:
分子量::
117.15
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
推薦產品
品質等級
化驗
98%
折射率
n20/D 1.4404 (lit.)
密度
1.029 g/mL at 25 °C (lit.)
SMILES 字串
CNCC1OCCO1
InChI
1S/C5H11NO2/c1-6-4-5-7-2-3-8-5/h5-6H,2-4H2,1H3
InChI 密鑰
ZCCPVTVGEQLONB-UHFFFAOYSA-N
應用
2-Methylaminomethyl-1,3-dioxolane was used in the synthesis of N-[methyl(2-hydroxy-3,5-dimethylphenyl)]-N-methyl-N-methyl-1,3-dioxolaneamine (mpoa-H).
訊號詞
Warning
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
136.4 °F - closed cup
閃點(°C)
58 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Jakub Wojtaszak et al.
Dalton transactions (Cambridge, England : 2003), 43(6), 2424-2436 (2013-12-07)
The reaction of MgBu2, ZnEt2 or Ca(O(i)Pr)2 with 2 eq. of three-coordinating N-[methyl(2-hydroxy-3,5-dimethylphenyl)]-N-methyl-N-methyl-1,3-oxolaneamine (mpoa-H) or N-[methyl(2-hydroxy-3,5-di-tert-butylphenyl)]-N-methyl-N-methyl-1,3-oxolaneamine (tbpoa-H) gave neutral, monomeric [Mg(mpoa)2], [Zn(mpoa)2], [Zn(tbpoa)2], and [Ca(tbpoa)2] as white powders in 58-90% yields. The resulting aminophenolates were characterized in solution by NMR
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