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Key Documents

272213

Sigma-Aldrich

环丙甲醛

98%

同義詞:

1-(甲酰基)环丙烷, 2-环丙烷甲醛, 环丙基甲醛, 环丙烷甲醛, 甲酰环丙烷

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About This Item

線性公式:
C3H5CHO
CAS號碼:
分子量::
70.09
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.4298 (lit.)

bp

98-101 °C (lit.)

密度

0.938 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

O=CC1CC1

InChI

1S/C4H6O/c5-3-4-1-2-4/h3-4H,1-2H2

InChI 密鑰

JMYVMOUINOAAPA-UHFFFAOYSA-N

相關類別

應用

环丙甲醛通过与[Ni(cod)(2)](cod = 1,5-环辛二烯)和PBu(3)反应,可合成eta(2)-烯酮镍配合物
用于制备环亚丙基四氢萘酮,其通过对映选择性钯催化的[3+2]TMM环加成反应,得到手性螺环稠合环戊烯。

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

44.6 °F - closed cup

閃點(°C)

7 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta(2)-enonenickel complexes (2 a-c). In the presence of PCy(3) (Cy =

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