推薦產品
等級
technical
化驗
≥97.0% (GC)
形狀
solid
顏色
deep brown
折射率
n20/D 1.635 (lit.)
n20/D 1.635
bp
167-169 °C/25 mmHg (lit.)
mp
32 °C (lit.)
密度
1.18 g/mL at 25 °C (lit.)
官能基
chloro
SMILES 字串
ClCc1cccc2ccccc12
InChI
1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
InChI 密鑰
XMWGTKZEDLCVIG-UHFFFAOYSA-N
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一般說明
Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類(WGK)
WGK 3
閃點(°F)
269.6 °F - closed cup
閃點(°C)
132 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
客戶也查看了
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)
Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
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