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Key Documents

245917

Sigma-Aldrich

五氟丙酸

97%

同義詞:

全氟丙酸

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About This Item

線性公式:
CF3CF2COOH
CAS號碼:
分子量::
164.03
Beilstein:
1773387
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

~5.6 (vs air)

蒸汽壓力

~40 mmHg ( 20 °C)

化驗

97%

形狀

liquid

折射率

n20/D 1.284 (lit.)

bp

96-97 °C (lit.)

密度

1.561 g/mL at 25 °C (lit.)

官能基

carboxylic acid

SMILES 字串

OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C3HF5O2/c4-2(5,1(9)10)3(6,7)8/h(H,9,10)

InChI 密鑰

LRMSQVBRUNSOJL-UHFFFAOYSA-N

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一般說明

五氟丙酸与氟原子的反应动力学已被研究

應用

五氟丙酸可用于制备2-五氟丙基喹唑啉-4(3H)-酮、全氟烷基硫醚 和含全氟烷基的3-氮杂双环[3.1.0]己烷。
五氟丙酸(全氟丙酸)被用于通过液相色谱(LC)法和Gemini色谱柱分析庆大霉素

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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E S Vasiliev et al.
The journal of physical chemistry. A, 118(23), 4013-4018 (2014-05-14)
The kinetics of the reaction between fluorine atoms and pentafluoropropionic acid has been studied experimentally at T = 262-343 K. The overall reaction rate constant decreases with temperature: k1(T) = 6.1 × 10(-13) exp(+1166 K)/T) cm(3) molecule(-1) s(-1). The potential
One-Pot Synthesis of Trifluoromethylated Quinazolin-4 (3 H)-ones with Trifluoroacetic Acid as CF3 Source
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The Journal of Organic Chemistry, 83(9), 5104-5113 (2018)
Synthesis of perfluoroalkyl thioethers from aromatic thiocyanates by iron-catalysed decarboxylative perfluoroalkylation
Exner, Benjamin and Bayarmagnai, Bilguun and Matheis, Christian and Goossen, Lukas J
Journal of Fluorine Chemistry, 198, 89-93 (2017)
Enantioselective C-H Functionalization-Addition Sequence Delivers Densely Substituted 3-Azabicyclo [3.1. 0] hexanes
Pedroni, Julia and Cramer, Nicolai
Journal of the American Chemical Society, 139(36), 12398-12401 (2017)
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Journal of chromatography. A, 1119(1-2), 285-293 (2006-03-21)
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