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Key Documents

238252

Sigma-Aldrich

1-碘癸烷

98%

同義詞:

癸基碘

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About This Item

線性公式:
CH3(CH2)9I
CAS號碼:
分子量::
268.18
Beilstein:
1735228
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

>5 (vs air)

品質等級

蒸汽壓力

0.01 mmHg ( 20 °C)

化驗

98%

形狀

liquid

包含

copper as stabilizer

折射率

n20/D 1.485 (lit.)

bp

132 °C/15 mmHg (lit.)

密度

1.257 g/mL at 25 °C (lit.)

SMILES 字串

CCCCCCCCCCI

InChI

1S/C10H21I/c1-2-3-4-5-6-7-8-9-10-11/h2-10H2,1H3

InChI 密鑰

SKIDNYUZJPMKFC-UHFFFAOYSA-N

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一般說明

Electrochemical reduction of 1-iododecane at mercury cathodes in DMF containing tetra-n-butylammonium perchlorate or tetramethyl ammonium perchlorate (supporting electrolyte) has been investigated.

應用

1-Iododecane has been used in the preparation of 9-nonadecanone via palladium-catalyzed carbonylative cross-coupling reaction with 9-octyl-9-borabicyclo[3.3.l]nonane.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

230.0 °F - closed cup

閃點(°C)

110 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


分析證明 (COA)

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Electrochemical reduction of 1-iododecane and 1-bromodecane at a mercury cathode in dimethylformamide.
McNamee GM, et al.
Journal of the American Chemical Society, 99(6), 1831-1835 (1977)
Palladium-catalyzed carbonylative cross-coupling reaction of iodoalkanes with 9-alkyl-9-BBN derivatives. A direct and selective synthesis of ketones.
Ishiyama T and Miyaura N.
Tetrahedron Letters, 32(47), 6923-6926 (1991)
Niluksha Walalawela et al.
Photochemistry and photobiology, 95(5), 1160-1168 (2019-03-19)
In order to develop a new long alkane chain pterin that leaves the pterin core largely unperturbed, we synthesized and photochemically characterized decyl pterin-6-carboxyl ester (CapC) that preserves the pterin amide group. CapC contains a decyl-chain at the carboxylic acid
Thomas Bielewicz et al.
Nanotechnology, 27(35), 355602-355602 (2016-07-28)
Two-dimensional colloidal nanosheets represent very attractive optoelectronic materials. They combine good lateral conductivity with solution-processability and geometry-tunable electronic properties. In the case of PbS nanosheets, so far synthesis has been driven by the addition of chloroalkanes as coligands. Here, we
Anthony N Cauley et al.
Biomaterials science, 5(10), 2114-2121 (2017-08-24)
We report a library of functionalized lignins and demonstrate their utility as nanocontainers for organic dyes in biologically relevant applications. Kraft lignin was modified via S

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