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217964

Sigma-Aldrich

四丁基四氟硼酸铵

99%

同義詞:

Ammonium tetra-n-butyl tetrafluoroborate

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About This Item

線性公式:
(CH3CH2CH2CH2)4N(BF4)
CAS號碼:
分子量::
329.27
Beilstein:
3577508
EC號碼:
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

powder

mp

155-161 °C (lit.)

溶解度

methanol: soluble 10%, clear, colorless

SMILES 字串

F[B-](F)(F)F.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.BF4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;/q+1;-1

InChI 密鑰

NNZZSJSQYOFZAM-UHFFFAOYSA-N

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一般說明

四氟硼酸四丁基铵被用作合成一系列芳基酮的电解质。

四丁基四氟硼酸铵(TBATFB)是相转移催化剂。它可以通过30%四氟硼酸水溶液与40%氢氧化四丁基铵水溶液反应合成。四丁基四氟硼酸铵可充当电解质,抑制烷基硫代硫酸盐在金上自组装。

應用

四丁基四氟硼酸铵可用于以下研究:
  • 作为伏安法测定Δ(9)-四氢大麻酚(Δ(9)-THC)的支持电解质。
  • 合成生物相关的大环内酯Sansalvamide A。
  • 作为循环伏安法测定5,10,15,20-四[3-(3-三氟甲基)苯氧基]卟啉的氧化和还原电位的支持电解质。
  • 与1,10-菲咯啉制备1:1加合物。
  • 用于在水溶液中制备其他四丁基铵盐。
  • 作为合成导电性聚(噻吩)的电解质添加剂。

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

No data available

閃點(°C)

No data available

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Preparation and properties of novel polythiophenes containing 1,3-dithiol-2-ylidene moieties.
Kozaki M, et al.
The Journal of Organic Chemistry, 59(2), 442-450 (1994)
Marco Antonio Balbino et al.
Forensic science international, 221(1-3), 29-32 (2012-04-25)
A new voltammetric method for the determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC) is described. The voltammetric experiments were accomplished in N-N dimethylformamide/water (9:1, v/v), using tetrabutylammonium tetrafluoroborate (TBATFB) 0.1mol/L as supporting electrolyte and a glassy carbon disk electrode as the working electrode.
Agnieszka Stolarczyk et al.
Sensors (Basel, Switzerland), 19(5) (2019-03-07)
In this study, polycarbazole (PCz) is presented as a receptor structure for chemoresistive hydrogen sensors. The fabrication of the proposed sensors via electropolymerisation of PCz on interdigitated Pt electrodes is an inexpensive, cost-efficient, and repeatable method. Preliminary results presented in
Rajesh G Pillai et al.
Langmuir : the ACS journal of surfaces and colloids, 27(14), 9028-9033 (2011-06-23)
Spontaneous self-assembly of alkylthiosulfates on gold produce monolayers similar to the corresponding alkanethiols. Alkylthiosulfate self-assembly from THF solutions is inhibited in the presence of tetrabutylammonium tetrafluoroborate electrolyte. The mechanism of alkylthiosulfate self-assembly and the role of electrolyte and trace water
José Antonio Morales-Serna et al.
Organic & biomolecular chemistry, 8(21), 4940-4948 (2010-09-08)
A facile and mild macrolactonization reaction of ω-hydroxy acids was developed based on the transesterification of benzotriazole esters. Treatment of ω-hydroxy acids with 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDC) and 1-hydroxy benzotriazole (HOBT) in chloroform provided macrolactones in excellent yields. The reactions were

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