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Merck
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重要文件

206563

Sigma-Aldrich

3-碘三氟甲苯

98%

同義詞:

3-碘-α,α,α-三氟甲苯

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About This Item

線性公式:
IC6H4CF3
CAS號碼:
分子量::
272.01
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

折射率

n20/D 1.517 (lit.)

bp

82-82.5 °C/25 mmHg (lit.)

密度

1.887 g/mL at 25 °C (lit.)

官能基

fluoro
iodo

SMILES 字串

FC(F)(F)c1cccc(I)c1

InChI

1S/C7H4F3I/c8-7(9,10)5-2-1-3-6(11)4-5/h1-4H

InChI 密鑰

IGISPMBUGPHLBY-UHFFFAOYSA-N

一般說明

Sonogashira coupling reaction between 3-iodobenzotrifluoride and phenylacetylene using a palladium system has been reported.

應用

3-Iodobenzotrifluoride was used in the preparation of zinc 5,10,15,20-tetrakis(3-(trifluoromethyl)phenylethynyl)porphyrin.

象形圖

Environment

危險聲明

防範說明

危險分類

Aquatic Chronic 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

158.0 °F - closed cup

閃點(°C)

70 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Rafael Luque et al.
Organic & biomolecular chemistry, 7(8), 1627-1632 (2009-04-04)
An efficient metal-free Sonogashira coupling protocol catalysed by DABCO is reported, where very good conversions and selectivities to the cross-coupling product were obtained under mild reaction conditions. The reported solvent-, phosphane- and metal-free protocol, that uses a cheap base as
Ming-Cheng Kuo et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1433-1439 (2007-03-28)
Sonogashira coupling of zinc 5,10,15,20-tetraethynylporphyrin with various phenyl iodides under mild conditions afforded good yields of the corresponding zinc porphyrins. This method is applicable to a variety of aryl iodides including meso-substituted iodoporphyrin to form a conjugated star-shaped multiporphyrin. The

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