推薦產品
品質等級
化驗
98%
形狀
liquid
折射率
n20/D 1.505 (lit.)
bp
90 °C/21 mmHg (lit.)
密度
1.116 g/mL at 25 °C (lit.)
官能基
fluoro
nitrile
SMILES 字串
Fc1ccccc1C#N
InChI
1S/C7H4FN/c8-7-4-2-1-3-6(7)5-9/h1-4H
InChI 密鑰
GDHXJNRAJRCGMX-UHFFFAOYSA-N
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一般說明
2-Fluorobenzonitrile reacts with lithium N,N-dialkylaminoborohydride reagent to yield 2-(N,N-dialkylamino)benzylamines.
應用
2-Fluorobenzonitrile was used in the synthesis of :
- 3-amino-1,2-benzisoxazoles
- 6-(acetylaminomethyl)-3-amino-1,2-benzisoxazole
- 5-(4′-methyl [1, 1′-biphenyl]-2-yl)-1H-tetrazole
- xanthone-iminium triflates
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
165.2 °F - closed cup
閃點(°C)
74 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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The Journal of organic chemistry, 66(6), 1999-2004 (2001-04-13)
A novel tandem amination-reduction reaction has been developed in which 2-(N,N-dialkylamino)benzylamines are generated from 2-halobenzonitriles and lithium N,N-dialkylaminoborohydride (LAB) reagents. These reactions are believed to occur through a tandem S(N)Ar amination-reduction mechanism wherein the LAB reagent promotes halide displacement by
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