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重要文件

195707

Sigma-Aldrich

顺式-1,4-二氯-2-丁烯

95%

同義詞:

(2Z)-1,4-Dichloro-2-butene, (2Z)-1,4-Dichlorobut-2-ene, (Z)-1,4-Dichloro-2-butene, 1,4-Dichloro-cis-2-butene, cis-1,2-Bis(chloromethyl)ethene

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About This Item

線性公式:
ClCH2CH=CHCH2Cl
CAS號碼:
分子量::
125.00
Beilstein:
1719692
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

95%

形狀

liquid

折射率

n20/D 1.489 (lit.)

bp

152 °C/758 mmHg (lit.)

mp

−48 °C (lit.)

密度

1.188 g/mL at 25 °C (lit.)

官能基

chloro

儲存溫度

2-8°C

SMILES 字串

ClC\C=C/CCl

InChI

1S/C4H6Cl2/c5-3-1-2-4-6/h1-2H,3-4H2/b2-1-

InChI 密鑰

FQDIANVAWVHZIR-UPHRSURJSA-N

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一般說明

cis-1,4-Dichloro-2-butene on reaction with sodium amide yields trans-1-chloro-1,3-butadiene. Mechanism of condensation of sulfone-activated methylene compounds with cis-1,4-dichloro-2-butene to yield cyclopentene has been investigated.

應用

cis-1,4-Dichloro-2-butene was used in the preparation of functionalized 3,5-disubstituted cyclopent-2-enones.

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

131.0 °F - closed cup

閃點(°C)

55 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Synthetic Communications, 17(1), 55-69 (1987)
Reactions of cis-and trans-1, 4-dichloro-2-butene with sodium amide.
Heasley VL and Lais BR.
The Journal of Organic Chemistry, 33(6), 2571-2572 (1968)
R J Gardner et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 23(1), 87-92 (1985-01-01)
Several important chemicals, including formaldehyde, 1,4-dichloro-2-butene, bis-chloromethyl ether, hexamethylphosphoramide, and epichlorohydrin have been shown to produce nasal tumours in rats following repeated or continuous inhalation exposures. Some of these compounds are respiratory irritants. To determine whether there is a correlation
L S Mullin et al.
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US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

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