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Merck
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文件

187879

Sigma-Aldrich

2,5-二甲氧基苯甲醇

99%

同義詞:

(2,5-Dimethoxyphenyl)methanol, 1-(Hydroxymethyl)-2,5-dimethoxybenzene, 2,5-Dimethoxybenzenemethanol

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About This Item

線性公式:
(CH3O)2C6H3CH2OH
CAS號碼:
分子量::
168.19
Beilstein:
1947607
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

折射率

n20/D 1.547 (lit.)

bp

122-125 °C/1 mmHg (lit.)

密度

1.173 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(OC)c(CO)c1

InChI

1S/C9H12O3/c1-11-8-3-4-9(12-2)7(5-8)6-10/h3-5,10H,6H2,1-2H3

InChI 密鑰

WGQMUABRZGUAOS-UHFFFAOYSA-N

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應用

2,5-Dimethoxybenzyl alcohol was used as starting reagent in the synthesis of [(S)S]-3,6-dimethoxy-2-(p-tolylsulfinyl)-benzaldehyde. It was used in the synthesis of daunornycinone. It was also used in the preparation of pillar[n]arenes (n = 5 or 6) via cyclooligomerization reaction with an appropriate Lewis acid catalyst.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


分析證明 (COA)

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An exceptional 5-endo-trig reversal; a convergent synthesis of daunomycinone.
Keay BA and Rodrigo R.
Canadian Journal of Chemistry, 61(3), 637-639 (1983)
Diastereodivergent additions of aluminum and magnesium reagents to [(S)S]-3, 6-dimethoxy-2-(p-tolylsulfinyl)-benzaldehyde.
Almori'n A, et al.
Tetrahedron Letters, 44(30), 5597-5600 (2003)
Preparation of Pillar [n] arenes by Cyclooligomerization of 2, 5-Dialkoxybenzyl Alcohols or 2, 5-Dialkoxybenzyl Bromides.
Ma Y, et al.
European Journal of Organic Chemistry, 2011(27), 5331-5335 (2011)

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