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Merck
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文件

184276

Sigma-Aldrich

2-溴苄醇

99%

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About This Item

線性公式:
BrC6H4CH2OH
CAS號碼:
分子量::
187.03
Beilstein:
2243418
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

solid

mp

78-80 °C (lit.)

SMILES 字串

OCc1ccccc1Br

InChI

1S/C7H7BrO/c8-7-4-2-1-3-6(7)5-9/h1-4,9H,5H2

InChI 密鑰

IOWGHQGLUMEZKG-UHFFFAOYSA-N

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應用

2-Bromobenzyl alcohol was used in microwave assisted palladium-catalyzed synthesis of phthalides. It was also used in the synthesis of 1-hydroxy-3(1H)-l,2-benzoboroxole.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves


分析證明 (COA)

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Synthesis and structure of benzoboroxoles: novel organoboron heterocycles.
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Tetrahedron Letters, 40(37), 6705-6708 (1999)
Fast microwave promoted palladium-catalyzed synthesis of phthalides from bromobenzyl alcohols utilizing DMF and Mo (CO)6 as carbon monoxide sources.
Wu X, et al.
Tetrahedron Letters, 45(24), 4635-4638 (2004)
Manas K Ghorai et al.
The Journal of organic chemistry, 79(14), 6468-6479 (2014-06-24)
A simple and unpredicted synthetic pathway toward racemic and scalemic tetrahydrodibenzoimidazoazepines has been invented serendipitously proceeding through an S(N)2-type ring-opening of N-activated aziridines with 2-bromobenzylamine followed by a hitherto unprecedented cascade cyclization reaction sequence comprising a Cu-catalyzed cross dehydrogenation C-N

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