推薦產品
蒸汽密度
6.6 (vs air)
品質等級
化驗
≥97.0% (HPLC)
品質
redist.
折射率
n20/D 1.52 (lit.)
n20/D 1.531
bp
265-270 °C (lit.)
溶解度
H2O: insoluble
alcohol: miscible
diethyl ether: miscible
密度
1.11 g/mL at 25 °C (lit.)
官能基
ester
ketone
phenyl
SMILES 字串
CCOC(=O)CC(=O)c1ccccc1
InChI
1S/C11H12O3/c1-2-14-11(13)8-10(12)9-6-4-3-5-7-9/h3-7H,2,8H2,1H3
InChI 密鑰
GKKZMYDNDDMXSE-UHFFFAOYSA-N
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應用
Ethyl benzoylacetate (Benzoylacetic acid ethyl ester) was used to prepare ethyl 2-fluoro-2-benzolyacetate. It was also used to synthesize iodonium ylides.
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
284.0 °F - closed cup
閃點（°C）
140 °C - closed cup
個人防護裝備
Eyeshields, Gloves
Tsugio Kitamura et al.
Organic letters, 13(9), 2392-2394 (2011-04-09)
A simple, practical, and convenient fluorination of 1,3-dicarbonyl compounds was achieved by direct use of aqueous hydrofluoric acid and iodosylbenzene (PhIO). The reaction of ethyl benzoylacetate with the reagent system of aqueous HF and PhIO in CH(2)Cl(2) gave ethyl 2-fluoro-2-benzolyacetate
Keisuke Gondo et al.
Molecules (Basel, Switzerland), 17(6), 6625-6632 (2012-06-26)
Reaction of dibenzoylmethane with (diacetoxyiodo)benzene in the presence of KOH in MeCN quantitatively gave the corresponding iodonium ylide, which was treated with a HF reagent to afford the corresponding 2-fluorinated dibenzoylmethane in 14-50% yields. The similar reaction of the iodonium
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