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Merck
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重要文件

124303

Sigma-Aldrich

叔丁基苯基碳酸酯

98%

同義詞:

1,1-Dimethylethyl phenyl carbonate, 1-tert-Butoxycarbonyloxybenzene, Phenyl tert-butyl carbonate

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About This Item

線性公式:
(CH3)3COCOOC6H5
CAS號碼:
分子量::
194.23
Beilstein:
2361602
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

bp

83 °C/0.6 mmHg (lit.)

密度

1.05 g/mL at 20 °C (lit.)

官能基

carbonate
phenoxy

SMILES 字串

CC(C)(C)OC(=O)Oc1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-10(12)13-9-7-5-4-6-8-9/h4-8H,1-3H3

InChI 密鑰

UXWVQHXKKOGTSY-UHFFFAOYSA-N

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應用

tert-Butyl phenyl carbonate was used in determination of octanol-water partition coefficients by microemulsion electrokinetic chromatography. It was also used in the synthesis of 2-nitroindoles. It was used as reagent for mono-Boc protection of α,ω-diamines.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

213.8 °F - closed cup

閃點(°C)

101.00 °C - closed cup

個人防護裝備

Eyeshields, Gloves


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分析證明 (COA)

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Organic Syntheses, 84, 209-209 (2007)
Jesper Østergaard et al.
Electrophoresis, 24(6), 1038-1046 (2003-03-27)
Microemulsion electrokinetic chromatography (MEEKC) was assessed as a tool for determination of octanol-water partition coefficients using 34 solutes encompassing 8 carbonate esters. It was confirmed that microemulsions containing 1.44-2.88% w/w SDS, 6.49% w/w 1-butanol, and 0.82% w/w n-heptane constitute a
Synthesis of 2-nitroindoles via the Sundberg indole synthesis.
Pelkey ET and Gribble GW.
Tetrahedron Letters, 38(32), 5603-5606 (1997)

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