推薦產品
品質等級
化驗
98%
折射率
n20/D 1.509 (lit.)
密度
1.017 g/mL at 25 °C (lit.)
SMILES 字串
C[Si](C)(Cl)c1ccccc1
InChI
1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3
InChI 密鑰
KWYZNESIGBQHJK-UHFFFAOYSA-N
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應用
用于手性硅基炔丙醇合成对映体富集联烯基硅烷的原酸酯克莱森重排反应。
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 1
閃點（°F）
143.6 °F - closed cup
閃點（°C）
62 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Carlton P Folster et al.
Dalton transactions (Cambridge, England : 2003), 49(45), 16125-16132 (2020-01-30)
The synthesis of a chloro-functionalized six-membered cyclosilazane (Si5N) is reported. Subsequent reductive polymerizations yielded low molecular weight polysilazanes. 1H and 29Si NMR characterization suggest the identity of the reducing metal influences the polysilazane structure. Optical characterization is consistent with extended
Ryan A Brawn et al.
Organic letters, 9(14), 2689-2692 (2007-06-15)
A convenient procedure for the synthesis of highly enantioenriched allenylsilanes by Johnson orthoester Claisen rearrangement of 1-silyl propargylic alcohols is described. Allenylsilanes are then used as carbon nucleophiles in three-component, Lewis acid mediated additions to in situ generated oxonium ions
M Okamoto
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 112(6), 409-413 (1992-06-01)
The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosilane in xylene, were studied by high-performance liquid chromatography using carbamazepine and diphenylhydantoin as model compounds. From the elemental
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