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![TRICYCLO[3.3.2.0(2,8)]DECA-3,6,9-TRIENE AldrichCPR](/deepweb/assets/sigmaaldrich/product/structures/514/889/34159289-e30a-4073-a31a-08ee96a8d1c3/640/34159289-e30a-4073-a31a-08ee96a8d1c3.png)
化驗
99%
折射率
n20/D 1.462 (lit.)
bp
136 °C (lit.)
密度
0.822 g/mL at 25 °C (lit.)
SMILES 字串
C\C=C1\CCCCC1
InChI
1S/C8H14/c1-2-8-6-4-3-5-7-8/h2H,3-7H2,1H3
InChI 密鑰
BPBOWYWUOUJKLO-UHFFFAOYSA-N
一般說明
Ethylidenecyclohexane is oxidized by purified ethylbenzene dehydrogenase.
應用
Ethylidenecyclohexane has been used as a substrate in the Lewis-acid catalyzed reactions of azodicarboxylates with different alkenes.
訊號詞
Warning
危險聲明
危險分類
Flam. Liq. 3
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
75.2 °F - closed cup
閃點（°C）
24 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
H A Johnson et al.
Journal of bacteriology, 183(15), 4536-4542 (2001-07-10)
The first step in anaerobic ethylbenzene mineralization in denitrifying Azoarcus sp. strain EB1 is the oxidation of ethylbenzene to (S)-(-)-1-phenylethanol. Ethylbenzene dehydrogenase, which catalyzes this reaction, is a unique enzyme in that it mediates the stereoselective hydroxylation of an aromatic
Pompiliu S Aburel et al.
Organic & biomolecular chemistry, 3(12), 2344-2349 (2005-07-13)
Lewis acids such as Cu(OTf)(2), Zn(OTf)(2), Yb(OTf)(3) and Nd(OTf)(3) catalyze the aza-ene reaction of alkenes with azodicarboxylates, giving the allylic amination adducts. The use of bis(2,2,2-trichloroethyl)azodicarboxylate as the amination reagent and Cu(OTf)(2) and Yb(OTf)(3) as the catalysts gave the aza-ene
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