CRM68466

Fluazifop-butyl

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Empirical Formula (Hill Notation): C₁₉H₂₀F₃NO₄
• CAS Number: 69806-50-4
• Molecular Weight: 383.36
• MDL number: MFCD00870330
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• quality: Racemate
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• storage temp.: -10 to -25°C
• SMILES string: CCCCOC(=O)C(C)Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1
• InChI: 1S/C19H20F3NO4/c1-3-4-11-25-18(24)13(2)26-15-6-8-16(9-7-15)27-17-10-5-14(12-23-17)19(20,21)22/h5-10,12-13H,3-4,11H2,1-2H3
• InChI key: VAIZTNZGPYBOGF-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma-aldrich.com

Fluazifop-butyl belongs to the class of aryloxyphenoxy-propionate (AOPP) herbicides that is used for postemergence control of annual and perennial grasses in a range of broad-leaved crops. When applied, this selective herbicide is absorbed by leaves and acts by inhibiting the acetyl-CoA carboxylase (ACCase) enzyme activity in plastids. Fluazifop-butyl rapidly degrades to the free acid form –fluazifop, a major chiral metabolite.

Fluazifop is not approved for use in European Union (EU) as per Regulation (EC) No 1107/2009. The maximum residue level (MRLs) for Fluazifop-P (sum of all the constituent isomers of fluazifop, its esters, and conjugates, expressed as fluazifop) has been set from 0.01 mg/kg to 9 mg/kg for products of plants and animal origin following Regulation (EU) 2018/1514.

Application

Fluazifop-butyl may be used as reference material for the following:

• Separation of the enantiomers of fluazifop-butyl and fluazifop by LC/MS/MS, followed by investigating the stereoselective degradation and transformation of the enantiomers of the herbicide fluazifop-butyl in soil and water
• To investigate the effects of herbicide fluazifop-butyl on broad-leaved weed, Acanthospermum hispidum, and study the mechanism of action of the herbicide on the weed
• To develop a residue analysis method for the determination of fluazifop-butyl and its chiral metabolite fluazifop in soil and vegetable and to investigate the enantioselective kinetics of fluazifop-butyl and the optical pure fluazifop-P-butyl
• To determine the mechanism of fluazifop-butyl action on bristly starbur and investigate the ethylene production and its involvement in lipid peroxidation of the membrane
• Simultaneous determination of fluazifop-butyl and fluazifop in soil samples using HPLC

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H360,H410
• Precautionary Statements: P202 - P273 - P280 - P308 + P313 - P391 - P405
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1B
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable